Precise Detection, Control and Synthesis of Chiral Compounds at Single-Molecule Resolution

Nano-Micro Letters

Perspective

Chen Yang¹  Weilin Hu¹  Xuefeng Guo² 

[1] Beijing National Laboratory for Molecular Sciences, National Biomedical Imaging Center, College of Chemistry and Molecular Engineering, Peking University, 292 Chengfu Road, Haidian District, 100871, Beijing, People’s Republic of China;Beijing National Laboratory for Molecular Sciences, National Biomedical Imaging Center, College of Chemistry and Molecular Engineering, Peking University, 292 Chengfu Road, Haidian District, 100871, Beijing, People’s Republic of China;Center of Single-Molecule Sciences, Institute of Modern Optics, Frontiers Science Center for New Organic Matter, College of Electronic Information and Optical Engineering, Nankai University, 38 Tongyan Road, Jinnan District, 300350, Tianjin, People’s Republic of China;

关键词: Single-molecule junction;    Molecular chirality;    Photonic polarization;    Electronic spin;    Asymmetric reaction;   

DOI  :  10.1007/s40820-023-01184-5

 received in 2023-05-23, accepted in 2023-08-10,  发布年份 2023

来源: Springer

【 摘 要 】

tsSingle-molecule electrical detection, especially the single-molecule junction setup, enables the precise detection and spatial operability of anchored molecules.The transition among asymmetric characteristics (i.e., molecular chirality, photonic polarization and electronic spin) is proposed as a universal methodology to realize the detection, control and synthesis of chirality.Exploring the origin of symmetry breaking contributes to the development of a general reliable strategy for asymmetric synthesis.

【 授权许可】

CC BY   
© Shanghai Jiao Tong University 2023

【 图 表 】

Fig. 1

40249_2023_1135_Article_IEq9.gif

40249_2023_1135_Article_IEq5.gif

Fig. 1

Fig. 3

Fig. 3

Fig. 1

Fig. 3