Structural characterization of char during co-gasification from torrefied sludge and Yangchangwan bituminous coal

International Journal of Coal Science & Technology

Research

Yonghui Bai¹  Guangsuo Yu²  Changbing Ye³  Jie Qin³  Jiazhong Liu³  Minhui Zhao³  Shuaibing Wang³  Shengli Shi³  Guiming Shi³  Xinsha Zhang⁴ 

[1] State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University, 750021, Yinchuan, China;State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University, 750021, Yinchuan, China;Institute of Clean Coal Technology, East China University of Science and Technology, 200237, Shanghai, China;Yuxi Normal University, 653100, Yuxi, Yunnan, China;Yuxi Normal University, 653100, Yuxi, Yunnan, China;State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University, 750021, Yinchuan, China;

关键词: Characteristic;    Char structure;    Torrefaction;    Co-gasification;   

DOI  :  10.1007/s40789-023-00638-w

 received in 2022-10-25, accepted in 2023-08-10,  发布年份 2023

来源: Springer

【 摘 要 】

The present study aims to investigate the physico-chemical structural evolution characteristics of char structure of CO2 atmosphere torrefaction pretreated sludge with Yangchangwan bituminous coal (YC) during co-gasification. The co-gasification reactivity of torrefied sludge and YC was measured using a thermogravimetric analyzer. The co-gasification reactivity of torrefied sludge with YC was thoroughly explored in depth by in situ heating stage microscope coupled with traditional characterization means of char sample (Scanning electron microscope, nitrogen adsorption analyzer, laser Raman spectroscopy). The results show that the gasification reaction rate of sludge treated under CO2 atmosphere and coal blended char was better than other char samples at 1100–1200 °C. The torrefied sludge under CO2 atmosphere promoted its thermal decomposition to the maximum extent, so that it eventually was transformed into a large number of small broken particles. The specific surface area and ID1/IG ratio of blended char of torrefied sludge under CO2 atmosphere and YC were 1.70 and 1.07 times higher than that of YC, respectively. The in situ technique revealed that YC char with the addition of torrefied sludge undergo gasification by shrinking core modes and the presence of obvious ash melting flow phenomenon. It was more obvious than that of YC.

【 授权许可】

CC BY   
© China Coal Research Institute 2023

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