Volumetric quantification of melting and solidification of phase change materials by in-situ X-ray computed tomography

卷:61

Article

关键词: THERMAL-ENERGY STORAGE;    TRANSITION;    PERFORMANCE;    HYSTERESIS;    ALGORITHM;    BEHAVIOR;    MODEL;    PCM;   

DOI  :  10.1016/j.est.2023.106726

来源: SCIE

【 摘 要 】

Solid-liquid phase transitions in phase change materials (PCM) usually exhibit a complex dynamics, which critically determines the performance of latent heat thermal energy storage systems (LHTES). Experimental approaches enabling to track the dynamics of the entire PCM solid-liquid phase transition are thus crucial to provide relevant data for PCM material development and to validate PCM-models used to design efficient LHTES. In this work, we show how in-situ dynamic X-ray computed tomography (XCT) can be used to track the dynamics of the solid-liquid phase transition in PCMs. The method based on time-lapse XCT is illustrated based on data collected for two PCMs (ice/water and calcium chloride hexahydrate) during melting and solidification processes, respectively. Key enabler of the method is the density difference between solid and liquid PCM, which facilitates a clear identification of the solid and liquid PCM phases and, thus, tracking their spatial evolution in time. Analysis of the transient liquid fraction curves reveals a volumetric melting rate of 0.55 (% vol)/min for ice with a total melting time of 165 min, whereas calcium chloride hexahydrate undergoes a partial solidification at -0.30 (% vol)/min, with an overall volumetric shrinkage of 12.7 %. Furthermore, an image-based approach to quantify the time-dependent liquid volume fraction curve from the sequences of XCT imaging data, is presented. The extracted liquid volume fraction curves capture the entire dynamics of the solid-liquid phase transition and can either be directly inserted in the mass and energy balance equations of currently existing PCM models to predict LHTES performance or used for PCM-models validation.

【 授权许可】

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