Water-resistant gum-based phase change composite for thermo-regulating insulation packaging

卷:61

Article

关键词: CELLULOSE NANOFIBRILS;    POLYETHYLENE;    RETARDANT;   

DOI  :  10.1016/j.est.2023.106725

来源: SCIE

【 摘 要 】

The world's current energy crisis calls for green energy solutions that can preserve energy while incorporating renewable. As such, we have developed a leakage-proof phase change material (PCM) embedded in a bio-polymeric matrix as a lightweight yet strong bio-based phase change composite (PCC) for passive energy storage and insulation purposes in packaging. This bio-based composite consists of gum tragacanth (GT) biopolymer and polyethylene glycol (PEG) PCM. It is further incorporated with biochar (BC) or mineral additive, i.e., Cloisite Na+, to enhance its mechanical strength and thermal stability, which are among the main challenges for insu-lation materials. A hydrophobic layer of octadecyl isocyanate (ODI) is developed on the surface of the composite to increase its water resistance. The composite provides a hydrophobic surface with a minor water uptake ca-pacity of 3.6 +/- 0.3 % after one-week immersion in the water. It shows high latent heat storage up to 160 J g-1 and a stable phase change behavior, as demonstrated by over 100 differential scanning calorimetry heating -cooling cycles. It also possesses notable compressive mechanical properties, which were improved signifi-cantly after incorporating BC and Cloisite Na+. The thermal conductivity of the composite is as low as 0.035 W m-1 K-1 manifesting in better thermal regulation compared with commercial polyethylene foams. This energy -positive bio-based solution combines the advantages of excellent insulation as a highly porous, lightweight, and strong composite with the latent heat and thermal inertia of PCM, making it suitable for transportation packaging of temperature-sensitive products.

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