Advances of manganese-oxides-based catalysts for indoor formaldehyde removal

卷:8

Review

关键词: VOLATILE ORGANIC-COMPOUNDS;    BIRNESSITE-TYPE MNO2;    ROOM-TEMPERATURE OXIDATION;    DENSITY-FUNCTIONAL THEORY;    IN-SITU SYNTHESIS;    ACTIVATED CARBON;    GASEOUS FORMALDEHYDE;    AIRBORNE FORMALDEHYDE;    HYBRID NANOSTRUCTURE;    DIOXIDE NANOSHEETS;   

DOI  :  10.1016/j.gee.2022.01.008

来源: SCIE

【 摘 要 】

Formaldehyde (HCHO) has been identified as one of the most common indoor pollutions nowadays. Manganese oxides (MnOx) are considered to be a promising catalytic material used in indoor HCHO oxidation removal due to their high catalytic activity, low-cost, and environmentally friendly. In this paper, the progress in developing MnOx-based catalysts for HCHO removal is comprehensively reviewed for exploring the mechanisms of catalytic oxidation and catalytic deactivation. The catalytic oxidation mechanisms based on three typical theory models (Mars-van-Krevelen, Eley-Rideal and Langmuir-Hinshelwood) are discussed and summarized. Furthermore, the research status of catalytic deactivation, catalysts' regeneration and integrated application of MnOx-based catalysts for indoor HCHO removal are detailed in the review. Finally, the technical challenges in developing MnOx-based catalysts for indoor HCHO removal are analyzed and the possible research direction is also proposed for overcoming the challenges toward practical application of such catalysts. (c) 2022 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).