Impact of yttrium hydride formation on multi-isotopic hydrogen retention by a getter trap for the DONES lithium loop

Nuclear Fushion

article

E. Carella¹  S.J. Hendricks¹  J. Molla¹  F.R. Urgorri¹ 

[1] Ciemat

关键词: DONES;    hydrogen trap;    yttrium getter;    liquid lithium;    hydrogen diffusion;    tritium transport modeling;    metal hydrides;   

DOI  :  10.1088/1741-4326/acc31a

来源: Institute of Physics Publishing Ltd.

【 摘 要 】

Compliance with imposed hydrogen concentration limits in the lithium loop of the DEMO-Oriented Neutron Source (DONES) requires the installation of an yttrium-based hydrogen trap. To determine an appropriate H-trap design, it is essential to have access to a numerical tool capable of simulating hydrogen transport in the DONES lithium loop connected to an yttrium pebble-bed. In the past, a simplified model was created that allows such calculations when hydrogen concentrations in the lithium are low. However, in certain DONES operating phases, the concentration in the lithium is high and in a range where yttrium dihydride (YH₂) formation is likely. Due to the anticipated great impact of YH₂ formation on the H-trap performance a new model is developed that includes the mechanism of hydride formation. It is based on a mathematical reproduction of complete pressure-composition isotherms of the Li–H and Y–H systems. Thus, the conditions that trigger YH₂ formation are determined and the variation of hydrogen solubility in different yttrium hydride phases is deduced. An approximate concentration-dependent relationship of hydrogen diffusivity in yttrium is derived and incorporated into the model. Simulations are performed to analyze the dynamics of the concentration decrease during purification of the lithium circuit prior to the experimental DONES phase by varying design parameters of the trap. It is found that hydride formation greatly increases the hydrogen gettering capacity of the H-trap and limits the maximum concentration in the lithium. Indeed, YH₂ formation may be purposefully triggered to exploit its beneficial properties for DONES. Simulations of the hydrogen purification process during the experimental phase of DONES show that the H-trap must be replaced at least every 28 days to meet tritium limits. This work sets the conditions for the required pebble-bed mass of the H-trap at a given temperature to comply with the DONES safety requirements. Finally, the model is validated by numerical reproduction of experimental results.

【 授权许可】

Unknown