The Free Energy of Mixing for a Binary Lattice Solution Consisting of Two Identical Interpenetrating Sublattices

Journal of the Korean Chemical Society

article

Hae Young Jung¹ 

[1]Department of Chemistry, Duksung Women’s University

关键词: Lattice theory;    Regular solution;    Nonrandom mixing;    Liquid-liquid equilibria;   

DOI  :  10.5012/jkcs.2022.66.4.278

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

Using the Kirkwood’s method, the free energy of a binary lattice solution consisting of two identical interpenetrating sublattices, such as a simple cubic lattice or a body-centered cubic lattice, was calculated up to the tenth order of thereciprocal of absolute temperature. Using this, liquid-liquid coexistence curves and critical solution temperatures for the binary lattice solutions were calculated to quantitatively investigate the effect of non-random mixing of molecules. And it was shown that thecoexistence curve of the simple cubic lattice solution was in good agreement with the Monte-Carlo computer simulation result.

【 授权许可】

Unknown