Exciton-phonon coupling and band-gap renormalization in monolayer WSe2

Article

关键词: TRANSITION-METAL DICHALCOGENIDES;    VALLEY COHERENCE;    EXCITATIONS;    STATES;    MOS2;   

DOI  :  10.1103/PhysRevB.98.045143

来源: SCIE

【 摘 要 】

Using a fully ab initio methodology, we demonstrate how the lattice vibrations couple with neutral excitons in monolayer WSe2 and contribute to the nonradiative excitonic lifetime. We show that only by treating the electron-electron and electron-phonon interactions at the same time is it possible to obtain an unprecedented agreement of the zero-and finite-temperature optical gaps and absorption spectra with the experimental results. The bare energies were calculated by solving the Kohn-Sham equations, where as G(0)W(0) many-body perturbation theory was used to extract the excited-state energies. A coupled electron-hole Bethe-Salpeter equation was solved incorporating the polaronic energies to show that it is the in-plane torsional acoustic phonon branch that contributes mostly to the A and B exciton buildup. We find that the three A, B, and C excitonic peaks exhibit different behavior with temperature, displaying different nonradiative linewidths. There is no considerable transition in the strength of the excitons with temperature, but the A exciton remains dark in comparison with the C exciton. Further, all the excitonic peaks redshift as temperature rises. Renormalization of the bare electronic energies by phonon interactions and anharmonic lattice thermal expansion causes a decreasing band gap with increasing temperature. The zero-point energy renormalization (31 meV) is found to be entirely due to the polaronic interaction with a negligible contribution from lattice anharmonicities. These results may have a profound impact on electronic and optoelectronic device technologies based on these monolayers.

【 授权许可】

Free