Anisotropic field-induced gap in the quasi-one-dimensional antiferromagnet KCuMoO4(OH)

Article

关键词: SPIN-ROTATION MEASUREMENTS;    TOTAL-ENERGY CALCULATIONS;    MAGNETIC-FIELD;    CU BENZOATE;    S=1/2;    CHAIN;    DYNAMICS;    TEMPERATURE;    EXCHANGE;   

DOI  :  10.1103/PhysRevB.96.104429

来源: SCIE

【 摘 要 】

We investigated magnetic and thermodynamic properties of S = 1/2 quasi-one-dimensional antiferromagnet KCuMoO4(OH) through single-crystalline magnetization and heat capacity measurements. At zero field, it behaves as a uniform S = 1/2 Heisenberg antiferromagnet with J = 238 K, and exhibits a canted antiferromagnetism below T-N = 1.52 K. In addition, a magnetic field H induces the anisotropy in magnetization and opens a gap in the spin-excitation spectrum. These properties are understood in terms of an effective staggered field induced by staggered g tensors and Dzyaloshinsky-Moriya (DM) interactions. Temperature dependencies of the heat capacity and their field variations are consistent with those expected for quantum sine-Gordon model, indicating that spin excitations consist of soliton, antisoliton, and breather modes. From field dependencies of the soliton mass, the staggered field normalized by the uniform field c(s) is estimated as 0.041, 0.174, and 0.030, for H || a, b, and c, respectively. Such a large variation of c(s) is understood as the combination of staggered g tensors and DM interactions which induce the staggered field in the opposite direction for H || a and c but almost the same direction for H || b at each Cu site.

【 授权许可】

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