Model of large volumetric capacitance in graphene supercapacitors based on ion clustering

Article

关键词: GRAPHITE-INTERCALATION COMPOUNDS;    ELECTROCHEMICAL INTERCALATION;    ELASTIC INTERACTIONS;    CHARGE;    RENORMALIZATION;    DENSITY;    STATES;   

DOI  :  10.1103/PhysRevB.84.235133

来源: SCIE

【 摘 要 】

Electric double-layer supercapacitors (SCs) are promising devices for high-power energy storage based on the reversible absorption of ions into porous conducting electrodes. Graphene is a particularly good candidate for the electrode material in SCs due to its high conductivity and large surface area. In this paper, we consider SC electrodes made from a stack of graphene sheets with randomly inserted spacer molecules. We show that the large volumetric capacitances C greater than or similar to 100 F/cm(3) observed experimentally can be understood as a result of collective intercalation of ions into the graphene stack and the accompanying nonlinear screening by graphene electrons that renormalizes the charge of the ion clusters.

【 授权许可】

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