Pressure-induced two-step spin transition with structural symmetry breaking: X-ray diffraction, magnetic, and Raman studies

Article

关键词: ISING-LIKE MODEL;    CROSSOVER COMPOUNDS;    INTERMEDIATE PHASE;    IRON(II) COMPLEXES;    THERMAL HYSTERESIS;    II COMPLEXES;    TEMPERATURE;    CONVERSION;    COMPOUND;    STATES;   

DOI  :  10.1103/PhysRevB.84.144107

来源: SCIE

【 摘 要 】

We have used single-crystal x-ray diffraction, Raman spectroscopy, and magnetometry to investigate the effect of hydrostatic pressures up to 16 kbar on the molecular spin crossover complex [Fe-II(bapbpy)(NCS)(2)]. A stepped first-order transition from the high-spin (HS) to low-spin (LS) phase was observed upon compression of single-crystal samples. The intermediate phase (IP) is stable between 4 and 11 kbar at room temperature. This phase is characterized by supercell reflections and tripling of the c-axis of the unit cell (C2/c) due to the formation of a periodic [HS-LS-LS] structural motif, as seen in the thermal stepped transition. The pressure-temperature phase diagram reveals an anomalous increase of the thermal hysteresis widths with increasing pressure and the stabilization of the IP across the investigated P-T space.

【 授权许可】

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