Synthesis, crystal structure, and magnetism of beta-Fe1.00(2)Se1.00(3) single crystals

Article

关键词: SUPERCONDUCTIVITY;   

DOI  :  10.1103/PhysRevB.83.224502

来源: SCIE

【 摘 要 】

Understanding iron-based superconductors requires high-quality impurity-free single crystals. So far they have been elusive for beta-FeSe and extraction of intrinsic materials properties has been compromised by several magnetic-impurity phases. Here, we report synchrotron-clean beta-FeSe superconducting single crystals grown via LiCl/CsCl flux method. Phase purity yields evidence for a defect-induced weak ferromagnetism that coexists with superconductivity below T-c. In contrast to Fe1+y Te-based superconductors, our results reveal that the interstitial Fe(2) site is not occupied and that all contribution to density of states at the Fermi level must come from in-plane Fe(1).

【 授权许可】

Free