Wetting layer of copper on the tantalum (001) surface | |
Article | |
关键词: X-RAY-DIFFRACTION; DIFFUSION BARRIER; FAILURE-MECHANISM; CU; DIFFRACTOMETER; FILMS; METALS; | |
DOI : 10.1103/PhysRevB.94.235427 | |
来源: SCIE |
【 摘 要 】
The heteroepitaxial interface formed by copper deposited onto the tantalum (001) surface is studied by surface x-ray diffraction and ab initio calculations. The analysis of the crystal truncation rods reveals the presence of a wetting layer of copper made of two atomic planes pseudomorphic to the tantalum substrate, with the upper most atomic planes significantly deformed. These findings are in total agreement with the results of density-functional-theory calculations. The presence of the wetting layer confirms a Stranski-Krastanov growth mode and is thought to explain the extremely fast atomic diffusion of copper during the dewetting process in the solid state at high temperature.
【 授权许可】
Free