Relativistic effects in homogeneous gold catalysis

Review

关键词: CYCLOISOMERIZATION REACTIONS;    INTRAMOLECULAR HYDROARYLATION;    INTERMOLECULAR HYDROAMINATION;    RAUTENSTRAUCH REARRANGEMENT;    SKELETAL REORGANIZATION;    THEORETICAL CHEMISTRY;    REDUCTIVE ELIMINATION;    ORGANOGOLD COMPLEXES;    CHEMICAL-PROPERTIES;    CHIRALITY TRANSFER;   

DOI  :  10.1038/nature05592

来源: SCIE

【 摘 要 】

Transition-metal catalysts containing gold present new opportunities for chemical synthesis, and it is therefore not surprising that these complexes are beginning to capture the attention of the chemical community. Cationic phosphine-gold(I) complexes are especially versatile and selective catalysts for a growing number of synthetic transformations. The reactivity of these species can be understood in the context of theoretical studies on gold; relativistic effects are especially helpful in rationalizing the reaction manifolds available to gold catalysts. This Review draws on experimental and computational data to present our current understanding of homogeneous gold catalysis, focusing on previously unexplored reactivity and its application to the development of new methodology.

【 授权许可】

Free