Reticular synthesis and the design of new materials

Review

关键词: METAL-ORGANIC FRAMEWORKS;    3-DIMENSIONAL COORDINATION POLYMER;    SECONDARY BUILDING UNITS;    CRYSTAL-STRUCTURE;    PHASE-TRANSITION;    PORE-SIZE;    CHEMISTRY;    SOLIDS;    NETWORK;    SORPTION;   

DOI  :  10.1038/nature01650

来源: SCIE

【 摘 要 】

The long-standing challenge of designing and constructing new crystalline solid-state materials from molecular building blocks is just beginning to be addressed with success. A conceptual approach that requires the use of secondary building units to direct the assembly of ordered frameworks epitomizes this process: we call this approach reticular synthesis. This chemistry has yielded materials designed to have predetermined structures, compositions and properties. In particular, highly porous frameworks held together by strong metal-oxygen-carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.

【 授权许可】

Free