Operando optical tracking of single-particle ion dynamics in batteries

Article

关键词: INTERFEROMETRIC SCATTERING MICROSCOPY;    X-RAY-DIFFRACTION;    IN-SITU;    CHARGE HETEROGENEITY;    LITHIUM DIFFUSION;    LICOO2;    INTERCALATION;    KINETICS;    ELECTRODE;    FILMS;   

DOI  :  10.1038/s41586-021-03584-2

来源: SCIE

【 摘 要 】

The key to advancing lithium-ion battery technology-in particular, fast charging-is the ability to follow and understand the dynamic processes occurring in functioning materials under realistic conditions, in real time and on the nano- to mesoscale. Imaging of lithium-ion dynamics during battery operation (operando imaging) at present requires sophisticated synchrotron X-ray(1-7) or electron microscopy(8,9) techniques, which do not lend themselves to high-throughput material screening. This limits rapid and rational materials improvements. Here we introduce a simple laboratory-based, optical interferometric scattering microscope(10-13) to resolve nanoscopic lithium-ion dynamics in battery materials, and apply it to follow cycling of individual particles of the archetypal cathode material(14,15), LixCoO2, within an electrode matrix. We visualize the insulator-to-metal, solid solution and lithium ordering phase transitions directly and determine rates of lithium diffusion at the single-particle level, identifying different mechanisms on charge and discharge. Finally, we capture the dynamic formation of domain boundaries between different crystal orientations associated with the monoclinic lattice distortion at the Li0.5CoO2 composition(16). The high-throughput nature of our methodology allows many particles to be sampled across the entire electrode and in future will enable exploration of the role of dislocations, morphologies and cycling rate on battery degradation. The generality of our imaging concept means that it can be applied to study any battery electrode, and more broadly, systems where the transport of ions is associated with electronic or structural changes. Such systems include nanoionic films, ionic conducting polymers, photocatalytic materials and memristors.

【 授权许可】

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