Croatica Chemica Acta | |
Click Reactivity of Azide-Modified PolyvinylChloride as an Entry to Glycopolymer Scaffolds | |
article | |
Ay, Emriye1  Yenil, Nilgün1  | |
[1] Manisa Celal Bayar University, Sciences & Arts Faculty, Department of Chemistry, Muradiye Campus | |
关键词: protected-sugar alkynes; PVC-N3; click reactions; 1; 2; 3-triazole.; | |
DOI : 10.5562/cca3883 | |
学科分类:化学(综合) | |
来源: Croatica Chemica Acta | |
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【 摘 要 】
We report the synthesis of new carbohydrate/triazole polymers based on poly(viny chloride) (PVC). Azide incorporation intocommercially available PVC was carried out using nucleophilic substitution and Cu-catalyzed reaction of the resulting PVC-N3 using three alkynylcontaining acetonide-protected monosaccharides (based on D-glucose and D-galactose) provided a set of PVC-based polymers incorporating atriazolyl linkage with monosaccharide moieties present on the periphery. Modified polymers were characterized by using Fourier transforminfrared (FT-IR), Nuclear Magnetic Resonance (1H-NMR and 13C-NMR) spectroscopy, together with thermogravimetric and surfacemorphological analysis.
【 授权许可】
CC BY
【 预 览 】
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