Halogen Storage Electrode Materials for Rechargeable Batteries

Energy & Environmental Materials

article

Zhiyang Xue¹  Zhengyuan Gao¹  Xiangyu Zhao¹ 

[1] State Key Laboratory of Materials-Oriented Chemical Engineering, Jiangsu Collaborative Innovation Center for Advanced Inorganic Functional Composites, College of Materials Science and Engineering, Nanjing Tech University

关键词: dual-ion batteries;    electrode materials;    halide-ion batteries;    halogen storage;    rechargeable batteries;   

DOI  :  10.1002/eem2.12442

来源: Wiley

【 摘 要 】

The ever-increasing demand for rechargeable batteries with high energy density, abundant resources, and high safety has pushed the development of various battery technologies based on cation, anion, or dual-ion transfer. The use of halogen storage electrode materials has led to new concept battery systems such as halide-ion batteries (HIB) and dual-ion batteries (DIB). This review highlights the recent progress on these electrode materials, including metal (oxy)halides, layered double hydroxides, MXenes, graphite-based materials, and organic materials with carbon or nitrogen redox centers. The reversible electrochemical halogen storage of halide ions (e.g., F − , Cl − , and Br − ), dual halogen (e.g., Br m Cl n and [ICl 2 ] − ), or binary halide anions (e.g., PF 6 − , AlCl 4 − , [ZnCl x ] 2−x , and [MgCl x ] 2−x ) in the electrodes is covered. The challenges and mechanisms of halogen storage in various electrode materials in HIBs and DIBs are summarized and analyzed, providing insights into the development of high-performance halogen storage electrode materials for rechargeable batteries.

【 授权许可】

Unknown