Purifying of Waste Tire Pyrolysis Oil Using an S-ZrO2/SBA-15-H2O2 Catalytic Oxidation Method

Catalysts

HoonChae Park¹  MuhammadNobi Hossain¹  HangSeok Choi¹  MyungKyu Choi¹ 

[1] Department of Environmental Engineering, Yonsei University, Wonju 26493, Korea;

关键词: optimization;    oxidative desulfurization;    taguchi method;    waste tire oil;   

DOI  :  10.3390/catal10040368

来源: DOAJ

【 摘 要 】

Heavy fuel oils contain a high amount of sulfur. In this work, an extent amount of sulfur content waste tire pyrolysis oil (WTPO) was used as a fuel feedstock. A promising alternative oxidative desulfurization (ODS) method was applied in sulfur removal from WTPO using a S-ZrO₂/SBA-15 solid acid catalyst, hydrogen peroxide (H₂O₂) as an oxidant and acetonitrile as an extracting solvent at varied conditions. The prepared catalyst was characterized by X-ray diffraction (XRD), Bruanuer-Emmet-Teller (BET) method and Fourier transform infrared spectroscopy (FTIR) analysis. The influence of reaction parameters such as reaction time (30-60 min), catalyst loading (0.5–1.5 wt.%), oxidant to oil mole ratio (5–15) at fixed reaction temperature 70 °C on desulfurization of WTPO were investigated. Taguchi method was selected to design the experiment for optimizing the reaction parameters by maximizing the sulfur removal efficiency. The maximum desulfurization efficiency 59.49% was obtained under optimum conditions reaction time (60 min), catalyst loading (1.0 wt.%) and oxidant to sulfur mole ratio (10:1). A catalytic S-ZrO₂/SBA-15 -H₂O₂ oxidation system for oxidative desulfurization of waste tire pyrolysis oil using at mild reaction conditions was developed.

【 授权许可】

Unknown