Correlation between the Crosslink Characteristics and Mechanical Properties of Natural Rubber Compound via Accelerators and Reinforcement

Polymers

KwanHo Seo¹  DongYun Lee¹  JaeWoo Park¹  DoYoung Kim¹ 

[1] Department of Polymer Science and Engineering, Kyungpook National University, Daegu 41566, Korea;

关键词: natural rubber;    crosslink characteristics;    mechanical properties;    thermal aging;    accelerator;    reinforcement agent;   

DOI  :  10.3390/polym12092020

来源: DOAJ

【 摘 要 】

The extreme elasticity and reversible deformability of rubber, which is one of the most versatile polymers in modern society, is dependent on several factors, including the processing conditions, curing system, and types of additives used. Since the rubber’s mechanical properties are influenced by the existing structural crosslinks, their correlation with the crosslink characteristics of rubber was investigated using the equilibrium swelling theory of the Flory–Rehner equation and the rubber–filler interaction theory of the Kraus equation. Herein, we examined whether the accelerator and reinforcement agent quantitatively contributed to chemical cross-linkages and rubber–filler interaction. In conclusion, the accelerator content supported the chemically crosslinked structures of the monosulfides and the disulfides in natural rubber (NR). Additionally, these results demonstrated that the mechanical properties and the thermal resistance of NR were dependent on the crosslink characteristics. The findings of this study provide an insight into the development and application of NR products for the mechanical optimization of rubber-based products.

【 授权许可】

Unknown