One Step Synthesis of NiO Nanoparticles via Solid-State Thermal Decomposition at Low-Temperature of NovelAqua(2,9-dimethyl-1,10-phenanthroline)NiCl2 Complex

International Journal of Molecular Sciences

Ahmed Boshaala¹  Mousa Al-Noaimi²  Assem Barakat³  Ismail Warad⁴  Mohammed Suleiman⁴  Salim F. Haddad⁵  Abdullah S. Aldwayyan⁶  Taibi Ben Hadda⁷  Belkheir Hammouti⁸ 

[1] Department of Chemistry, Faculty of Science, Benghazi University, P.O. Box 1308,Benghazi 5341, Libya;Department of Chemistry, Hashemite University, Zarqa 13115, Jordan;Department of Chemistry, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia;Department of Chemistry, Science College, AN-Najah National University, P.O. Box 7,Nablus, Palestine;Department of Chemistry, the University of Jordan, Amman 11942, Jordan;Department of Physics and Astronomy, King Saud University, P.O. Box 2455, Riyadh 11451,Saudi Arabia;Lab of Chemical Material, FSO, University Mohammed Premier, Oujda 60000, Morocco;Laboratoire de Chimie Appliquée et Environnement, LCAE-URAC18, Faculity of Science, University Mohammed Premier, Oujda 60000, Morocco;

关键词: nickel(II) complex;    thermal decomposition;    2,9-dimethyl-1,10-phenanthroline;    nanoparticles;   

DOI  :  10.3390/ijms141223941

来源: DOAJ

【 摘 要 】

[NiCl2(C14H12N2)(H2O)] complex has been synthesized from nickelchloride hexahydrate (NiCl2·6H2O) and 2,9-dimethyl-1,10-phenanthroline (dmphen) asN,N-bidentate ligand. The synthesized complex was characterized by elemental analysis, infrared (IR) spectroscopy, ultraviolet-visible (UV-vis) spectroscopy and differential thermal/thermogravimetric analysis (TG/DTA). The complex was further confirmed by single crystal X-ray diffraction (XRD) as triclinic with space group P-1. The desired complex, subjected to thermal decomposition at low temperature of 400 °C in an open atmosphere, revealed a novel and facile synthesis of pure NiO nanoparticles with uniform spherical particle; the structure of the NiO nanoparticles product was elucidated on the basis of Fourier transform infrared (FT-IR), UV-vis spectroscopy, TG/DTA, XRD, scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDXS) and transmission electron microscopy (TEM).

【 授权许可】

Unknown