Influence of electrochemical conditions on the regio- and stereoselectivity of selenocyclization of alkenyl hydantoins

Journal of the Serbian Chemical Society

Simić Zoran¹  Stanić Petar B.¹  Joksović Ljubinka G.¹  Šmit Biljana M.²  Ašanin Darko P.² 

[1] Faculty of Science, University of Kragujevac, Kragujevac, Serbia;Institute for Information Technologies, University of Kragujevac, Kragujevac, Serbia;

关键词: electrosynthesis;    constant-current electrolysis;    selenylation;    ring closure;   

DOI  :  10.2298/JSC201022023S

来源: DOAJ

【 摘 要 】

5-Alkenyl hydantoins and alkenyl spirohydantoins are converted into bicyclic and tricyclic hydantoins, under indirect electrochemical conditions, generating the phenylselenyl cation in situ. The reactions proceeded in good to exelent yields. The influence of electrochemical conditions on regio- and diastereoselectivity of the selenocyclization reactions is investigated.

【 授权许可】

Unknown