Arenediazonium salts transformations in water media: Coming round to origins

Resource-Efficient Technologies

Ksenia V. Kutonova¹  Victor D. Filimonov¹  Marina E. Trusova¹  Pavel S. Postnikov²  Victor V. Kurtukov² 

[1] Department of Biotechnology and Organic Chemistry, National Research Tomsk Polytechnic University, 634050 Tomsk, Russia;Department of Technology of Organic Substances and Polymer Materials, National Research Tomsk Polytechnic University, 634050 Tomsk, Russia;

关键词: Diazonium salts;    Green chemistry;    Arylation;    Halogenation;    Cross-coupling;   

DOI  :  10.1016/j.reffit.2016.01.001

来源: DOAJ

【 摘 要 】

Aromatic diazonium salts belong to an important class of organic compounds. The chemistry of these compounds has been originally developed in aqueous media, but then chemists focused on new synthetic methods that utilize reactions of diazonium salts in organic solvents. However, according to the principles of green chemistry and resource-efficient technologies, the use of organic solvents should be avoided. This review summarizes new trends of diazonium chemistry in aqueous media that satisfy requirements of green chemistry and sustainable technology.

【 授权许可】

Unknown