期刊论文详细信息
Molecules | |
Synthesis and Reactivity of Martin’s Spirosilane-Derived Chloromethylsilicate | |
Jérémy Forte1  Gilles Lemière1  Louis Fensterbank1  Thomas Deis1  | |
[1]CNRS, Institut Parisien de Chimie Moléculaire, IPCM, Sorbonne Université, 4 Place Jussieu, F-75005 Paris, France | |
关键词: silicon; spirosilane; pentacoordination; Sila-Matteson rearrangement; DFT calculations; | |
DOI : 10.3390/molecules27061767 | |
来源: DOAJ |
【 摘 要 】
Pentacoordinate silicon derivatives with a chloromethyl ligand are versatile compounds that are usually obtained from the corresponding tetravalent trialkoxy- or trihalogeno(chloromethyl)silane. We describe herein the synthesis of a chloromethylsilicate bearing two Martin’s ligands readily obtained by addition of in situ generated chloromethyllithium to a spirosilane. The reactivity of this new species was evaluated and it has been established that the chloride is displaced by strong nucleophiles such as alkyllithiums and (hetero)aryllithiums. In Lewis acidic conditions, the pentacoordinate silicon species rearranges through a formal insertion of a methylene into one Si–C bond, to form a new tetravalent spirosilane with a six-membered ring. The same kind of rearrangement can be triggered also by addition of a Lewis base. The mechanism of the rearrangement in both conditions has been studied by means of DFT calculations.【 授权许可】
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