Synthesis and crystal structure of (E)-2-benzyl-1,3-diphenylisothiouronium iodide

Acta Crystallographica Section E: Crystallographic Communications

Chee-Hun Kwak¹  Taek Hyeon Kim²  Sungmin Kang² 

[1] Department of Chemistry Education, Sunchon National University, 255 Jungang-ro, Sunchon, 57922, South Korea;School of Chemical Engineering, College of Engineering, Chonnam National, University, Gwangju, 61186, South Korea;

关键词: crystal structure;    thioether;    n—h...i hydrogen bonding;   

DOI  :  10.1107/S2056989021013086

来源: DOAJ

【 摘 要 】

In the title molecular salt, C20H19N2S+·I−, prepared by the reaction of 1,3-diphenylthiourea and benzyl iodide, the C—S—C thioether bond angle is 101.66 (9)° and electrons are delocalized over the N+= C—N skeleton. The dihedral angle between the aromatic rings attached to the N atoms is 40.60 (9)°. In the crystal, N—H...I hydrogen bonds link the components into [100] chains.

【 授权许可】

Unknown