Molten salt-supported polycondensation of optically active diacid monomers with an aromatic thiazole-bearing diamine using microwave irradiation

Journal of Advanced Research

Amin Zadehnazari¹  Shadpour Mallakpour¹ 

[1] Organic Polymer Chemistry Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran;

关键词: Nanostructure polymers;    Poly(amide-imide)s;    Thermal stability;    Molten salt;    Polycondensation;   

DOI  :  10.1016/j.jare.2013.04.003

来源: DOAJ

【 摘 要 】

Microwave heating was used to prepare optically active thiazole-bearing poly(amide-imide)s. Polymerization reactions were carried out in the molten tetrabutylammonium bromide as a green molten salt medium and triphenyl phosphite as the homogenizer. Structural elucidation of the compounds was performed by Fourier transform infrared and NMR spectroscopic data and elemental analysis results. The polymeric samples were readily soluble in various organic solvents, forming low-colored and flexible thin films via solution casting. They showed high thermal stability with decomposition temperature being above 360 °C. They were assembled randomly in a nanoscale size.

【 授权许可】

Unknown