Copper-Catalyzed Dimerization/Cyclization of Itaconates

Molecules

Ruirui Li¹  Zhiqiang Li¹  Zhengning Li¹  Lan Jiang¹ 

[1] College of Environmental and Chemical Engineering, Dalian University, Dalian 116622, China;

关键词: copper;    catalysis;    domino reaction;    itaconate;    dimerization;    cyclopentanone;   

DOI  :  10.3390/molecules200815023

来源: DOAJ

【 摘 要 】

A copper-catalyzed domino reaction between itaconate esters and diethyl zinc(or silane) is developed, affording itaconate dimerization products, multi-ester-substituted cyclopentanones, in moderate to high yields.

【 授权许可】

Unknown