Spatial and Temporal Evolution of Groundwater Chemistry of Baotu Karst Water System at Northern China

Minerals

Wen Liu¹  Guangqi Lin¹  Lijun Ma²  Chunfang Jiang²  Jiancong Fang²  Xingzhou Zhang²  Changsuo Li²  Chengcheng Li²  Xiubo Zhang²  Xin Zhang²  Xubo Gao² 

[1] 801 Institute of Hydrogeology and Engineering Geology, Shandong Provincial Bureau of Geology & Mineral Resources, Jinan 250014, China;Institute of Geological Survey & School of Environmental Studies, China University of Geosciences, Wuhan 430074, China;

关键词: karst water;    karst aquifer minerals;    water–rock interaction;    groundwater quality;    Baotu spring;   

DOI  :  10.3390/min12030348

来源: DOAJ

【 摘 要 】

Karst water quality degradation has been a challenge for domestic and industrial water supplies worldwide. To reveal the possible factors response for karst water quality degradation, Baotu karst spring system is studied as an representative example. In this study, a hydrogeochemical investigation and mathematical, statistical, and geochemical modeling was conducted together to identify the major hydrochemical processes involved in the degradation process. It is found that the karst water is normally fresh, neutral-to-slightly alkaline, with calcium and magnesium as the predominant cations, and bicarbonate and sulfate as the predominant anions. The abnormally high chloride (95.05 mg/L) and nitrate concentrations (148.4 mg/L) give clues to the potential source of contamination in some karst water. The main hydrochemical facies of karst water are HCO₃-Ca and HCO₃ × SO₄-Ca, accounting for 76% of water samples. The water hydrochemistry is controlled mainly by the dissolution of carbonate minerals (calcite, dolomite), followed by the dissolution of silicate and gypsum. The dissolution of calcite and dolomite mostly happens in the recharge area. In the discharge area, the karst water is basically in equilibrium with calcite. The negative SI value of gypsum represents that the water–gypsum interaction is dominated by dissolution along the whole flow path. Cation exchange is observed in the karst water in the indirect recharge area. Along the flow path, the contents of chloride, sulfate, nitrate, and TDS (Total dissolved solids, abbreviated TDS, indicates how many milligrams of dissolved solids are dissolved in one liter of water) vary significantly, which is mostly affected by pollution from human industrial and agricultural activities. The concentrations of major ions were maintained at a low level (<20 mg/L) in the 1960s in karst water. The fast elevation of the parameter values has occurred in the past two decades. The temporal elevation of some pollutants in karst water suggest that global changes (acid rain) and human activity (such as overusing fertilizer) are main factors resulting in the degradation of karst water quality in the study area. The results of this paper provide invaluable information for the management and protection of karst water resources in the urban and rural areas.

【 授权许可】

Unknown