Microstructure Evolution in a Solid Oxide Fuel Cell Stack Quantified with Interfacial Free Energy

Energies

Janusz S. Szmyd¹  Grzegorz Brus¹  Tomasz A. Prokop¹ 

[1] Department of Fundamental Research in Energy Engineering, AGH University of Science and Technology, 30-059 Krakow, Poland;

关键词: solid oxide fuel cell;    microstructure;    phase field model;    degradation;   

DOI  :  10.3390/en14123476

来源: DOAJ

【 摘 要 】

Degradation of electrode microstructure is one of the key factors affecting long term performance of Solid Oxide Fuel Cell systems. Evolution of a multiphase system can be described quantitatively by the change in its interfacial energy. In this paper, we discuss free energy of a microstructure to showcase the anisotropy of its evolution during a long-term performance experiment involving an SOFC stack. Ginzburg Landau type functional is used to compute the free energy, using diffuse phase distributions based on Focused Ion Beam Scanning Electron Microscopy images of samples taken from nine different sites within the stack. It is shown that the rate of microstructure evolution differs depending on the position within the stack, similar to phase anisotropy. However, the computed spatial relation does not correlate with the observed distribution of temperature.

【 授权许可】

Unknown