Synthesis of clay geopolymers using olive pomace fly ash as an alternative activator. Influence of the additional commercial alkaline activator used

Journal of Materials Research and Technology

P.J. Sánchez-Soto¹  F.J. Moral-Moral²  M.A. Gómez-Casero²  L. Pérez-Villarejo³  D. Eliche-Quesada⁴ 

[1] Center for Advanced Studies in Earth Sciences, Energy and Environment (CEACTEMA), University of Jaén, Campus Las Lagunillas, s/n, 23071, Jaén, Spain;Department of Chemical, Environmental, and Materials Engineering, Higher Polytechnic School of Jaén, University of Jaén, Campus Las Lagunillas s/n, 23071, Jaén, Spain;Department of Chemical, Environmental, and Materials Engineering, Higher Polytechnic School of Linares, University of Jaén, Campus Científico-Tecnológico, Cinturón Sur s/n, 23700, Linares (Jaén), Spain;Institute of Materials Science of Sevilla (ICMS), Joint Center of the Spanish National Research Council (CSIC), University of Sevilla, 41092, Sevilla, Spain;

关键词: Geopolymers;    Clay;    Olive pomace fly ash;    Valorization;    Alkaline activator;    Sustainability;   

DOI  :  

来源: DOAJ

【 摘 要 】

In this research, the use of olive pomace fly ash (OPFA) as an alkaline source for the activation of calcined clays (CC) from Bailén (Jaén, Spain) was studied. The optimal composition was obtained for 70 wt % CC and 30 wt % OPFA. The physical, mechanical and thermal properties of control geopolymers that use water as a liquid medium have been studied and compared with geopolymers that use additional activating solutions as sodium or potassium hydroxide solutions (8 M), or a mixture of alkaline hydroxide and alkaline silicate solution (NaOH–Na2SiO3 or KOH–K2SiO3). The results showed that OPFA can be used as an alkaline activator, showing mechanical properties slightly lower than those obtained when additional alkaline hydroxide activating solutions were used. The best compressive strength was obtained for geopolymers that use alkaline silicates as an activating solution. However, the best thermal insulation properties were obtained for control geopolymers. The microstructural characteristics of the geopolymers were evaluated by means of X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy and Scanning Electron Microscopy (SEM-EDS) that corroborate the formation of geopolymeric gel in all the specimens, being the amount of gel formed greater in samples using commercial potassium activating solutions. These results demonstrate the feasibility of using this type of waste, OPFA, as activating reagents in the manufacture of geopolymers or alkaline activated materials. The manufactured geopolymers can be used as compressed earth blocks for walls and partitions, since the specimens pursue mechanical properties that comply with current regulations, presenting better thermal insulation properties.

【 授权许可】

Unknown