Molecular interaction studies of the volumetric behavior of binary liquid mixtures containing alcohols

Journal of the Serbian Chemical Society

Đorđević Bojan D.¹  Šerbanović Slobodan P.¹  Radović Ivona R.¹  Tasić Aleksandar Ž.¹  Kijevčanin Mirjana Lj.¹ 

[1] Tehnološko-metalurški fakultet, Beograd;

关键词: molecular interactions;    volumetric properties;    excess volume;    alcohols;    binary liquid mixtures;   

DOI  :  10.2298/JSC0905477D

来源: DOAJ

【 摘 要 】

An attempt has been made to relate the volumetric effects involved in the binary mixtures of normal and branched alcohols and various components (aromatics, halo and nitroaromatics and haloaliphatics) with the molecular interactions of unlike molecules. This review is a condensation of research activities developed in recent years as results of a better understanding of volumetric behavior and a stronger insight into the complex structure of those mixtures. The influence of important contributions of a physical, chemical and geometrical nature that change excess molar volume, VE (positive, sigmoidal, negative) is considered and explained in detail. It appears that the balance between these contributions is quite sensitive to the behavior of the alcohol molecules in contact with the chosen compounds.

【 授权许可】

Unknown