[(1,2,5,6-η)-Cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene-κC2)(triphenylphosphane-κP)iridium(I) tetrafluoridoborate

IUCrData

Sue A. Roberts¹  Karam B. Idrees²  Edward Rajaseelan²  William J. Rutledge² 

[1] Department of Chemistry and Biochemistry, The University of Arizona, Tuscon, AZ 85716, USA;Department of Chemistry, Millersville University, Millersville, PA 17551, USA;

关键词: crystal structure;    iridium complex;    imidazole;    cycloocta-1,5-diene;   

DOI  :  10.1107/S2414314617014110

来源: DOAJ

【 摘 要 】

In the title compound, [Ir(C8H12)(C8H14N2)(C18H15P)]BF4, the cationic complex has the anticipated square-planar geometry. The asymmetric unit comprises the iridium complex and one tetrafluoridoborate anion. The space group is non-centrosymmetric, with the Flack parameter of 0.007 (3) well determined, and confirms the hand for the complex cation. This compound shows promising catalytic activity in transfer hydrogenation reactions.

【 授权许可】

Unknown