Targeted Cross-Section Calculations for Plasma Simulations

Atoms

Jonathan Tennyson¹  Sebastian Mohr²  Maria Tudorovskaya²  Martin Hanicinec² 

[1] Department of Physics and Astronomy, University College, Gower St., London WC1E 6BT, UK;Quantemol Ltd., 320 Angel, 320 City Road, London EC1V 2NZ, UK;

关键词: cross-section calculations;    R-matrix;    plasma simulation;   

DOI  :  10.3390/atoms9040085

来源: DOAJ

【 摘 要 】

Gathering data on electron collisions in plasmas is a vital part of conducting plasma simulations. However, data on neutral radicals and neutrals formed in the plasma by reactions between different radicals are usually not readily available. While these cross-sections can be calculated numerically, this is a time-consuming process and it is not clear from the outset which additional cross-sections are needed for a given plasma process. Hence, identifying species for which additional cross-sections are needed in advance is highly advantageous. Here, we present a structured approach to do this. In this, a chemistry set using estimated data for unknown electron collisions is run in a global plasma model. The results are used to rank the species with regard to their influence on densities of important species such as electrons or neutrals inducing desired surface processes. For this, an algorithm based on graph theory is used. The species ranking helps to make an informed decision on which cross-sections need to be calculated to improve the chemistry set and which can be neglected to save time. The validity of this approach is demonstrated through an example in an SF${}_6$/O${}_2$ plasma.

【 授权许可】

Unknown