Diisopropylammonium (3,6-dichlorobenzene-1,2-dithiolato)cuprato(III) tetrahydrofuran monosolvate

IUCrData

Diego Hernández¹  Jesús Barrio¹  Félix Zamora¹  Esther Delgado¹  Elisa Hernández¹  Josefina Perles² 

[1] Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid, Spain;Laboratorio de Difracción de Rayos X de Monocristal, SIdI, Universidad Autónoma de Madrid, 28049 Madrid, Spain;

关键词: crystal structure;    copper(III) dithiolate;    coordination compound;    ammonium;    hydrogen bonding;   

DOI  :  10.1107/S2414314616018836

来源: DOAJ

【 摘 要 】

The asymmetric unit of the title compound, (C6H16N)[Cu(C6H2Cl2S2)2]·C4H8O, comprises a [Cu(SC6H2Cl2S)2]− anion, an [iPr2NH2]+ cationand a solvent tetrahydrofuran molecule. The CuIII atom has an almost square-planar CuS4 coordination environment. In the crystal, the anion and the solvent molecule are linked via N—H...O and N—H...S hydrogen bonds involving the diisopropylammonium cation. There are no other significant intermolecular interactions present.

【 授权许可】

Unknown