Cationic Axial Ligand Effects on Sulfur-Substituted Subphthalocyanines

Molecules

Yusaku Ogura¹  Masahiro Nakano¹  Taniyuki Furuyama¹  Masahito Segi¹  Hajime Maeda¹ 

[1] Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan;

关键词: subphthalocyanine;    axial ligand;    absorption spectra;    fluorescence;    ionization potential;   

DOI  :  10.3390/molecules27092766

来源: DOAJ

【 摘 要 】

Herein, we report the synthesis of sulfur-substituted boron(III) subphthalocyanines (SubPcs) with cationic axial ligands. Subphthalocyanines were synthesized by a condensation reaction using the corresponding phthalonitriles and boron trichloride as a template. An aminoalkyl group was introduced on the central boron atom; this process was followed by N-methylation to introduce a cationic axial ligand. The peripheral sulfur groups shifted the Q band of SubPcs to a longer wavelength. The cationic axial ligands increased the polarity and enhanced the hydrophilicity of SubPcs. The effect of axial ligands on absorption and fluorescence properties is generally small. However, a further red shift was observed by introducing cationic axial ligands into the sulfur-substituted SubPcs. This change is similar to that in sulfur-substituted silicon(IV) phthalocyanines. The unique effect of the cationic axial ligand was extensively investigated by theoretical calculations and electrochemistry. In particular, the precise oxidation potential was determined using ionization potential measurements. Thus, the results of the present study provide a novel strategy for developing functional dyes and pigments based on SubPcs.

【 授权许可】

Unknown