Crystal structure of aqua[N-(2-oxidobenzyl-κO)-l-leucinato-κ2N,O](1,10-phenanthroline-κ2N,N′)nickel(II) pentahydrate

Acta Crystallographica Section E: Crystallographic Communications

Md. Serajul Haque Faizi¹  Natalia O. Sharkina² 

[1] Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, UP 208 016, India;National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv, Ukraine;

关键词: crystal structure;    nickel(II) complex;    hydrogen bonding;   

DOI  :  10.1107/S2056989015001085

来源: DOAJ

【 摘 要 】

In the title compound, [Ni(C13H17NO3)(C12H8N2)(H2O)]·5H2O, the NiII atom is in a distorted octahedral coordination environment provided by the two N atoms of one bidentate phenanthroline ligand and two O atoms and one N atom from a tridentate 2-[(2-hydroxybenzyl)amino]-4-methylpentanoic acid (HAMA) ligand and one water molecule. The complex was prepared by the reaction of nickel(II) nitrate with HAMA in the presence of 1,10-phenanthroline in a 1:1:1 ratio. In the crystal, the complex molecules and solvate water molecules are associated via O—H...O hydrogen bonds into a three-dimensional network.

【 授权许可】

Unknown