Comparison of Same Carbon Chain Length Cationic and Anionic Surfactant Adsorption on Silica

Colloids and Interfaces

Pengxiang Li¹  Tiejian Li¹  Yang Su¹  Munehide Ishiguro² 

[1]Department of Hydraulic Engineering, Tsinghua University, Beijing 100084, China

[2]Laboratory of Soil Conservation, Research Faculty of Agriculture, Hokkaido University, Sapporo 060-8589, Japan

关键词: dodecyl pyridinium chloride;    adsorption;    zeta potential;    sodium dodecyl sulfate;    silica;   

DOI  :  10.3390/colloids4030034

来源: DOAJ

【 摘 要 】

Adsorption of a cationic surfactant dodecyl pyridinium chloride (DPC) on silica was studied to show a comparison with the adsorption of an anionic surfactant sodium dodecyl sulfate (SDS), whose carbon chain length is the same and on the same silica. Results provided a better understanding of the adsorption mechanism of cationic and anionic surfactant on negatively charged silica. The experiment covered different electrolyte concentrations and pH values. Results indicated that at the same pH, the DPC adsorption amounts are higher when the electrolyte concentration is higher; at a higher DPC equilibrium concentration, the adsorption amount difference is larger than that at low DPC equilibrium concentration, and when DPC equilibrium concentration is lower than 0.1 mmol/L, the adsorption amount difference cannot be observed. At charge compensation point (CCP, 0 zeta potential), the negative surface charge of silica was compensated by DP⁺, a continuous increasing zeta potential indicated a bilayer adsorption of DPC on silica. The adsorption amount increased with increasing pH. The calculated lines by Gu and Zhu model show a two-step property, including a bilayer and hemi-micelle adsorption. DPC adsorbed more strongly on silica than SDS due to the combination of electrostatic and hydrophobic attraction.

【 授权许可】

Unknown