The template synthesis, spectral characterization and thermal behavior of new binuclear Schiff base complexes derived from N-aminopyrimidine with 2,3-butandion

Journal of the Serbian Chemical Society

Şekerci Memet¹  Sönmez Mehmet² 

[1] Department of Chemistry, Faculty of Science and Arts, Firat University, Elaziğ, Turkey;Department of Chemistry, Faculty of Science and Arts, Yüzüncü Yil, Van, Turkey;

关键词: acyclic schiff base complexes;    cu(ii);    co(ii);    ni(ii);    zn(ii) template synthesis;   

DOI  :  10.2298/JSC0703259S

来源: DOAJ

【 摘 要 】

Anew series of two types of acyclic binuclear Schiff base complexes, prepared by the template condensation of N-aminopyrimidine and 2,3-butandion in the presence of Cu(II), Ni(II), Co(II) and Zn(II) in n-BuOH solution, were analyzed and characterized by elemental analyses, IR and electronic spectroscopy, conductivity and magnetic measurements. From the conductivity measurements, it is concluded that the complex of NiII is a 1:1 type of electrolyte. All the complexes have sub-normal magnetic moments in accordance with their binuclear nature. The thermal behaviour of the complexes was studied by thermogravimetry.

【 授权许可】

Unknown