Surface and Microstructure Analysis of CoCrPt Film on RuCoCrX (X = Ti, Re) Intermediate Layers

Crystals

Jai-Lin Tsai¹  Ting-Wei Hsu¹  Jyun-You Chen¹  Cheng Dai¹  Shi-Min Weng¹ 

[1] Department of Materials Science and Engineering, National Chung Hsing University, Taichung 402, Taiwan;

关键词: perpendicular anisotropy;    intergrain interaction;    coercivity;   

DOI  :  10.3390/cryst10040263

来源: DOAJ

【 摘 要 】

The microstructural and magnetic properties of perpendicular anisotropic CoCrPt films deposited on Ru or RuCoCrX (X = Ti, Re) intermediate layers were studied. The c-axis of CoCrPt grains were promoted by (0002) textured RuCoCr, and RuCoCrX (X = Ti, Re) intermediate layers due to smaller lattice misfit as compared to Ru. The narrower rocking width (Δθ₅₀ = 3.76°) in RuCoCrRe intermediate layer and CoCrPt shows higher out of plane coercivity (H_c = 6.2 kOe), magnetic anisotropy constant (K_u = 6.2 × 10⁶ erg/cm³) and nucleation field (H_N = −2.8kOe) as compared to the Ru intermediate layer (H_c = 5.4 kOe, K_u = 5.9 × 10⁶ erg/cm³, H_N = −1.6 kOe). The partial intergranular exchange decoupling of CoCrPt grains was observed. The grain boundaries oxides were formed by the residual oxygen in targets and sputtering processes. The minor Cr₂O₃, CoO, TiO₂, ReO₃ oxides were investigated by surface analysis. Due to the minor oxides and Cr segregation at grains boundaries, the CoCrPt films present high coercivity. Samples CoCrPt/RuCoCr and CoCrPt/RuCoCrTi present a minimum at 45° but the values are much higher than the ideal Stoner-Wohlfarth theoretical value 0.5 which could be due to fewer natural oxides for magnetic grains separation. In sample CoCrPt/RuCoCrRe, there is an increase of intergranular interaction as indicated by the large asymmetry and the shift of the minimum at lower angles.

【 授权许可】

Unknown