Hybrid Porous Crystalline Materials from Metal Organic Frameworks and Covalent Organic Frameworks

Advanced Science

Ziman Chen¹  Tianwei Tan¹  Yongqin Lv¹  Kaipeng Cheng¹  Xinle Li²  Chongqing Yang³  Yi Liu³ 

[1] Beijing Key Laboratory of Bioprocess College of Life Science and Technology Beijing University of Chemical Technology Beijing 100029 China;Department of Chemistry Clark Atlanta University Atlanta GA 30314 USA;The Molecular Foundry Lawrence Berkeley National Laboratory Berkeley CA 94720 USA;

关键词: covalent organic frameworks;    hierarchical structures;    hybrids;    metal‐organic frameworks;    porous materials;   

DOI  :  10.1002/advs.202101883

来源: DOAJ

【 摘 要 】

Abstract Two frontier crystalline porous framework materials, namely, metal‐organic frameworks (MOFs) and covalent organic frameworks (COFs), have been widely explored owing to their outstanding physicochemical properties. While each type of framework has its own intrinsic advantages and shortcomings for specific applications, combining the complementary properties of the two materials allows the engineering of new classes of hybrid porous crystalline materials with properties superior to the individual components. Since the first report of MOF/COF hybrid in 2016, it has rapidly evolved as a novel platform for diverse applications. The state‐of‐art advances in the various synthetic approaches of MOF/COF hybrids are hereby summarized, together with their applications in different areas. Perspectives on the main challenges and future opportunities are also offered in order to inspire a multidisciplinary effort toward the further development of chemically diverse, multi‐functional hybrid porous crystalline materials.

【 授权许可】

Unknown