Investigating Lignin-Derived Monomers and Oligomers in Low-Molecular-Weight Fractions Separated from Depolymerized Black Liquor Retentate by Membrane Filtration

Molecules

Margareta Sandahl¹  Jens Prothmann¹  Charlotta Turner¹  Kena Li²  Sara Blomberg²  Christian Hulteberg² 

[1] Centre for Analysis and Synthesis, Department of Chemistry, Lund University, SE-22100 Lund, Sweden;Department of Chemical Engineering, Lund University, SE-21100 Lund, Sweden;

关键词: black liquor retentate;    depolymerization;    identification;    monomer;    oligomers;   

DOI  :  10.3390/molecules26102887

来源: DOAJ

【 摘 要 】

Base-catalyzed depolymerization of black liquor retentate (BLR) from the kraft pulping process, followed by ultrafiltration, has been suggested as a means of obtaining low-molecular-weight (LMW) compounds. The chemical complexity of BLR, which consists of a mixture of softwood and hardwood lignin that has undergone several kinds of treatment, leads to a complex mixture of LMW compounds, making the separation of components for the formation of value-added chemicals more difficult. Identifying the phenolic compounds in the LMW fractions obtained under different depolymerization conditions is essential for the upgrading process. In this study, a state-of-the-art nontargeted analysis method using ultra-high-performance supercritical fluid chromatography coupled to high-resolution multiple-stage tandem mass spectrometry (UHPSFC/HRMSⁿ) combined with a Kendrick mass defect-based classification model was applied to analyze the monomers and oligomers in the LMW fractions separated from BLR samples depolymerized at 170–210 °C. The most common phenolic compound types were dimers, followed by monomers. A second round of depolymerization yielded low amounts of monomers and dimers, while a high number of trimers were formed, thought to be the result of repolymerization.

【 授权许可】

Unknown