Fixed-Bed Adsorption of Phenol onto Microporous Activated Carbon Set from Rice Husk Using Chemical Activation

Applied Sciences

Hilmi Mukhtar¹  Abdalhaleem A. Hassaballa²  Samah B. Daffalla²  Maizatul S. Shaharun³ 

[1] Department of Chemical Engineering, Universiti Teknologi PETRONAS, Tronoh 31750, Malaysia;Department of Environment and Agricultural Natural Resources, College of Agricultural and Food Sciences, King Faisal University, P.O. Box 400, Al-Ahsa 31982, Saudi Arabia;Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, Tronoh 31750, Malaysia;

关键词: activated carbon;    breakthrough curve;    column study;    phenol removal;    rice husk;   

DOI  :  10.3390/app12094354

来源: DOAJ

【 摘 要 】

In the course of this research, the potential of activated carbon from rice husk was examined as being a phenol removal medium from an aqueous solution in a fixed-bed adsorption column. The activated carbon was characterized through FESEM (Field-Emission Scanning Electron Microscopy) and BET (Brunauer–Emmett–Teller) surface area. According to the FESEM micrograph and BET surface area, RHAC (rice husk activated carbon) had a porous structure with a large surface area of 587 m²·g⁻¹ and mean diameter of pores of 2.06 nm. The concentration effects on the influent phenol (100–2000 mg·L⁻¹), rate of flow (5–10 mL·min⁻¹), and bed depth (8.5–15.3 cm) were examined. It was found that the capacity of bed adsorption increased according to the increase in the influent concentration and bed depth. However, the capacity of bed adsorption decreased according to the increase in the feed flow rate. The regeneration of activated carbon column using 0.1 M sodium hydroxide was found to be effective with a 75% regeneration efficiency after three regeneration cycles. Data on adsorption were observed to be in line with many well-established models (i.e., Yoon–Nelson and Adams–Bohart, as well as bed depth service time models).

【 授权许可】

Unknown