Characterization of Chemically Activated Pyrolytic Carbon Black Derived from Waste Tires as a Candidate for Nanomaterial Precursor

Nanomaterials

Marc Madou¹  ReynaBerenice González-González²  SergioO. Martinez-Chapa²  Sigfrido Iglesias-González²  Everardo González-González²  LucyT. González²  MarioMoisés Alvarez²  Alberto Mendoza² 

[1] Department of Mechanical and Aerospace Engineering, University of California, Irvine, CA 92697, USA;Tecnologico de Monterrey, Escuela de Ingeniería y Ciencias, Ave. Eugenio Garza Sada 2501, Monterrey 64849, N.L., Mexico;

关键词: particle characterization;    pyrolysis;    carbon dots;    valorization;    chemical activation;   

DOI  :  10.3390/nano10112213

来源: DOAJ

【 摘 要 】

Pyrolysis is a feasible solution for environmental problems related to the inadequate disposal of waste tires, as it leads to the recovery of pyrolytic products such as carbon black, liquid fuels and gases. The characteristics of pyrolytic carbon black can be enhanced through chemical activation in order to produce the required properties for its application. In the search to make the waste tire pyrolysis process profitable, new applications of the pyrolytic solid products have been explored, such as for the fabrication of energy-storage devices and precursor in the synthesis of nanomaterials. In this study, waste tires powder was chemically activated using acid (H₂SO₄) and/or alkali (KOH) to recover pyrolytic carbon black with different characteristics. H₂SO₄ removed surface impurities more thoroughly, improving the carbon black’s surface area, while KOH increased its oxygen content, which improved the carbon black’s stability in water suspension. Pyrolytic carbon black was fully characterized by elemental analysis, inductively coupled plasma–optical emission spectrometry (ICP-OES), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, X-ray diffraction (XRD), N₂ adsorption/desorption, scanning electron microscopy–energy-dispersive X-ray spectroscopy (SEM-EDS), dynamic light scattering (DLS), and ? potential measurement. In addition, the pyrolytic carbon black was used to explore its feasibility as a precursor for the synthesis of carbon dots; synthesized carbon dots were analyzed preliminarily by SEM and with a fluorescence microplate reader, revealing differences in their morphology and fluorescence intensity. The results presented in this study demonstrate the effect of the activating agent on pyrolytic carbon black from waste tires and provide evidence of the feasibility of using waste tires for the synthesis of nanomaterials such as carbon dots.

【 授权许可】

Unknown