Sulfonated magnetic carbon nanoparticles from eucalyptus oil as a green and sustainable catalyst for converting fructose to 5-HMF

Catalysis Communications

Jamekorn Panichpol¹  Tawatchai Charinpanitkul¹  Kantapong Arunaditya¹  Tanapat Rodruangnon¹  Giang T.T. Le¹  Sutarat Thongratkaew²  Kawisa Chaipojjana²  Kajornsak Faungnawakij² 

[1] Center of Excellence in Particle Technology and Material Processing, Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok, Thailand;National Nanotechnology Center, National Science and Technology Development Agency, Thailand Science Park, Patumtani, Thailand;

关键词: Sulfonated magnetic carbon nanoparticles;    Eucalyptus oil;    Fructose;    5-hydroxymethylfurfural;   

DOI  :  

来源: DOAJ

【 摘 要 】

Sulfonated magnetic carbon nanoparticles (SMCNs) were synthesized from eucalyptus oil via co-pyrolysis with ferrocene and sulfonation by H2SO4. Catalytic performance of SMCNs for conversion of fructose to 5-hydroxymethylfurfural was examined within a designated range of reaction temperature (120–180 °C) and time (30–240 min). 84% conversion of fructose and 51.6% yield of 5-hydroxymethylfurfural could be achieved with catalyst-to-fructose mass ratio of 0.167 at 180 °C and the reaction time of 30 min. The magnetic property of SMCNs also facilitated recovery and recycling of the spent catalyst. Additionally, more than 50% yield of 5-hydroxymethylfurfural could be achieved after three cycles.

【 授权许可】

Unknown