2-(5-Bromothiophen-2-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazole

IUCrData

T. Paramasivam Perumal¹  Sivakalai Mayakrishnan¹  Chandramouleeswaran Suvasini²  T. Kavitha²  Srinivasakannan Lakshmi² 

[1] Organic & Bioorganic Chemistry, CSIR–Central Leather Research Institute, Adyar, Chennai 600 020, India;Research Department of Physics, S.D.N.B. Vaishnav College for Women, Chrompet, Chennai 600 044, India;

关键词: crystal structure;    phenanthrene;    imidazole;    thiophene;    C—H...N and C—H...Br hydrogen bonding;    C—H...π interactions;   

DOI  :  10.1107/S241431461700089X

来源: DOAJ

【 摘 要 】

In the title molecule, C25H15BrN2S, the phenanthrene system is slightly skewed, with a dihedral angle of 8.94 (16)° between the outer benzene rings. The imidazole ring makes dihedral angles of 15.18 (16), 2.94 (15) and 88.46 (16)°, respectively, with the thiophene ring, the central benzene ring of the phenanthrene unit and the phenyl ring attached to the latter unit. In the molecule, there are two C—H...π interactions present involving the phenyl ring. In the crystal, molecules are linked by C—H...N and C—H...Br hydrogen bonds, forming zigzag chains along the a axis. The chains are linked by C—H...π interactions, forming a three-dimensional supramolecular structure.

【 授权许可】

Unknown