Frontiers in Materials | |
Crystallization of the Na2FexNi1−xP2O7 Glass and Ability of Cathode for Sodium-Ion Batteries | |
关键词: glass-ceramics; crystallization behavior; sodium-ion batteries; cathode materials; charge-discharge test; | |
DOI : 10.3389/fmats.2020.00034 | |
来源: DOAJ |
【 摘 要 】
Although the sodium phosphate cathode active materials based on the Ni3+/Ni2+ redox reaction are expected to develop a high discharge potential, none of the studies aimed at practical application have been reported due to its poor kinetics showed in the sodium phosphate. Herein, we substituted active Fe for a part of Ni, expecting to activate the potential deriving from the Ni3+/2+ in Na2FexNi1−xP2O7 glass-ceramics. Precursor glasses were prepared by the melt-quenching method and exhibited surface crystallization tendency due to heterogeneous nucleation. In the charge-discharge testing, all the flat potential showed in the discharge process derived from the reduction of Fe3+/2+. However, from the dQ/dV plot, there were two weak reduction peaks at 4.3 and 4.4 V in the discharge process of Na2Fe0.25Ni0.75P2O7. Combining with the oxidation peak at 4.6 V in the second charge process of Na2NiP2O7, we believe the reduction peaks at 4.3 and 4.4 V were derived from the Ni3+/2+.
【 授权许可】
Unknown