Porphyrin MOF-Derived Porous Carbons: Preparation and Applications

C

Flávio Figueira¹  FilipeA. Almeida Paz¹ 

[1] Department of Chemistry, CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal;

关键词: metal–organic frameworks;    porous carbons;    porphyrins;    electrochemistry;   

DOI  :  10.3390/c7020047

来源: DOAJ

【 摘 要 】

Metal–organic frameworks (MOFs) are crystalline materials with permanent porosity, composed of metal nodes and organic linkers whose well-ordered arrangement enables them to act as ideal templates to produce materials with a uniform distribution of heteroatom and metal elements. The hybrid nature of MOFs, well-defined pore structure, large surface area and tunable chemical composition of their precursors, led to the preparation of various MOF-derived porous carbons with controlled structures and compositions bearing some of the unique structural properties of the parent networks. In this regard, an important class of MOFs constructed with porphyrin ligands were described, playing significant roles in the metal distribution within the porous carbon material. The most striking early achievements using porphyrin-based MOF porous carbons are here summarized, including preparation methods and their transformation into materials for electrochemical reactions.

【 授权许可】

Unknown