Synthesis and Gas Transport Properties of Addition Polynorbornene with Perfluorophenyl Side Groups

Polymers

EugeneSh. Finkelshtein¹  MaximV. Bermeshev¹  IlyaL. Borisov¹  AlexeyV. Volkov¹  GlebO. Karpov¹ 

[1] A.V. Topchiev Institute of Petrochemical Synthesis of Russian Academy of Sciences, 29 Leninsky Prospekt, 119991 Moscow, Russia;

关键词: norbornenes;    addition polynorbornenes;    gas permeability;    membrane gas separation;   

DOI  :  10.3390/polym12061282

来源: DOAJ

【 摘 要 】

Polynorbornenes represent a fruitful class of polymers for structure–property study. Recently, vinyl-addition polynorbornenes bearing side groups of different natures were observed to exhibit excellent gas permeation ability, along with attractive C₄H₁₀/CH₄ and CO₂/N₂ separation selectivities. However, to date, the gas transport properties of fluorinated addition polynorbornenes have not been reported. Herein, we synthesized addition polynorbornene with fluoroorganic substituents and executed a study on the gas transport properties of the polymer for the first time. A norbornene-type monomer with a C₆F₅ group, 3-pentafluorophenyl-exo-tricyclononene-7, was successfully involved in addition polymerization, resulting in soluble, high-molecular-weight products obtained in good or high yields. By varying the monomer concentration and monomer/catalyst ratio, it was possible to reach M_w values of (2.93–4.35) × 10⁵. The molecular structure was confirmed by NMR and FTIR analysis. The contact angle with distilled water revealed the hydrophobic nature of the synthesized polymer as expected due to the presence of fluoroorganic side groups. A study of the permeability of various gases (He, H₂, O₂, N₂, CO₂, and CH₄) through the prepared polymer disclosed a synergetic effect, which was achieved by the presence of both bulky perfluorinated side groups and rigid saturated main chains. Addition poly(3-pentafluorophenyl-exo-tricyclononene-7) was more permeable than its metathesis analogue by a factor of 7–21, or the similar polymer with flexible main chains, poly(pentafluorostyrene), in relation to the gases tested. Therefore, this investigation opens the door to fluorinated addition polynorbornenes as new potential polymeric materials for membrane gas separation.

【 授权许可】

Unknown