Nanomaterials | |
The Performance and Mechanism of a Mg-Al Double-Layer Oxide in Chloride ion Removal from an Aqueous Solution | |
Xueqin Xu1  Xiangke Han2  Shichong Yang2  Peng Li2  Tong Zhang2  Guoli Zhou2  Daoguang Teng2  Yijun Cao2  | |
[1] Henan Province Industrial Technology Research Institution of Resources and Materials, Zhengzhou University, Zhengzhou 450001, China;School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China; | |
关键词: Mg-Al LDO; Cl− removal; adsorption kinetics; electrostatic adsorption; reusability; | |
DOI : 10.3390/nano12050846 | |
来源: DOAJ |
【 摘 要 】
The increasing threat of chloride ions (Cl−) has led researchers to explore efficient removal technologies. Sewage treatment with a double-layer hydroxide/oxide (LDH/LDO) is receiving increasing attention. In this work, Mg-Al LDO adsorbents were produced by the calcination of the Mg-Al LDH precursor, which was constituted by improved coprecipitation. The influence of calcination temperature, calcination time, adsorbent dosage, Cl− initial concentration, contact time, and adsorption temperature on Cl− elimination was investigated systematically. The experimental results showed that a better porous structure endowed the Mg-Al LDO with outstanding adsorption properties for Cl−. The adsorption process was well matched to the pseudo-second-order kinetics model and the Freundlich model. Under optimal conditions, more than 97% of the Cl− could be eliminated. Moreover, the removal efficiency was greater than 90% even after 11 adsorption–desorption cycles. It was found that the electrostatic interaction between Cl− and the positively charged Mg-Al LDO laminate, coupled with the reconstruction of the layer structure, was what dominated the Cl− removal process.
【 授权许可】
Unknown