期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure and DFT study of bis{(S)-2-[(2-hydroxybenzyl)amino]-4-methylpentanoato-κ2N,O}(1,10-phenanthroline-κ2N,N′)nickel(II) | |
Md. Serajul Haque Faizi1  Sergey Malinkin2  Necmi Dege3  | |
[1] Department of Chemistry, College of Science, Sultan Qaboos University, PO Box 36 Al-Khod 123, Muscat, Sultanate of Oman;Department of Chemistry, National Taras Shevchenko University of Kiev, 64/13, Volodymyrska Street, City of Kyiv, 01601, Ukraine;Ondokuz Mayıs University, Arts and Sciences Faculty, Department of Physics, 55139 Atakum–Samsun, Turkey; | |
关键词: crystal structure; nickel(II); phenanthroline; amine; leucine; salicylaldehyde; C—H...π interactions; hydrogen bonding; | |
DOI : 10.1107/S2056989017012014 | |
来源: DOAJ |
【 摘 要 】
In the title compound, [Ni(C13H18NO3)2(C12H8N2)], the NiII cation shows a distorted octahedral coordination environment. It is formed by two N atoms from the phenanthroline ligand, as well as two N and two O atoms belonging to two 2-[(2-hydroxybenzyl)amino]-4-methylpentanoate ligands. Complex molecules are connected into layers propagating along the ab plane via hydrogen bonds formed by O atoms of carboxylate and phenoxide groups, which are further connected into a three-dimensional motif.
【 授权许可】
Unknown