Crystal structure and DFT study of bis{(S)-2-[(2-hydroxybenzyl)amino]-4-methylpentanoato-κ2N,O}(1,10-phenanthroline-κ2N,N′)nickel(II)

Acta Crystallographica Section E: Crystallographic Communications

Md. Serajul Haque Faizi¹  Sergey Malinkin²  Necmi Dege³ 

[1] Department of Chemistry, College of Science, Sultan Qaboos University, PO Box 36 Al-Khod 123, Muscat, Sultanate of Oman;Department of Chemistry, National Taras Shevchenko University of Kiev, 64/13, Volodymyrska Street, City of Kyiv, 01601, Ukraine;Ondokuz Mayıs University, Arts and Sciences Faculty, Department of Physics, 55139 Atakum–Samsun, Turkey;

关键词: crystal structure;    nickel(II);    phenanthroline;    amine;    leucine;    salicylaldehyde;    C—H...π interactions;    hydrogen bonding;   

DOI  :  10.1107/S2056989017012014

来源: DOAJ

【 摘 要 】

In the title compound, [Ni(C13H18NO3)2(C12H8N2)], the NiII cation shows a distorted octahedral coordination environment. It is formed by two N atoms from the phenanthroline ligand, as well as two N and two O atoms belonging to two 2-[(2-hydroxybenzyl)amino]-4-methylpentanoate ligands. Complex molecules are connected into layers propagating along the ab plane via hydrogen bonds formed by O atoms of carboxylate and phenoxide groups, which are further connected into a three-dimensional motif.

【 授权许可】

Unknown